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Explain why iron, cobalt and nickel do not show the expected highest oxidation states of +8, +9 and +10 respectively. |
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Answer» i. The oxidation states of an element depends on its electronic configuration and the number of unpaired electrons. ii. The electronic configuration of Fe, Co and Ni are as follows:
iii. Hence, the expected oxidation states of Fe, Co and Ni shall be +8, +9 and +10 respectively. iv. Fe by the loss of two electrons from 4s subshell forms Fe2+ and further loss of one more electron from 3d-orbital forms Fe3+, which is very stable due to half filled orbital, 3d5 . Hence, there is no further loss of electrons from the 3d subshell and thus Fe does not show +8 oxidation. v. Co forms Co2+ due to the loss of two electrons from 4s subshell and further loss of one more electron from 3d-orbital forms Co3+. In cobalt, +2 and +3 oxidation states are more stable and it does not lose electrons further. Hence, Co does not show +9 oxidation state. vi. Ni forms Ni2+ by the loss of two electrons from 4s-orbital and by the loss of one more electron from 3dorbital, it forms Ni3+. The amount of energy required for the ionization of Ni to Ni2+ is less when compared to that required for the ionization of Ni to Ni4+. Hence, Ni2+ oxidation state is comparatively more stable. There is no further loss of electrons and therefore, Ni does not show +10 oxidation state. |
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