1.

Explain why reactivity of benzene ring is increases due to presence of -OH group in phenol.

Answer»

SOLUTION :According to above structure of phenol, ortho and para position of -OH possess negative charge MEANS HIGH density of electrons. So electrophilic group react on ortho and para position.
(a) On resonance, electron PAIR of -OH group enter into the benzene ring, so electrophilic substitution reaction becomes easy in phenol with respect to benzene.
(b) -OH group has -I effect, so it will ATTRACT electrons of ring towards itself.

butstrengthof resonanceeffect` gt`strengthofinductiveeffect, soelectrondensityis moreinphenolis morereactivetowards. thebenzene ringof phenolis morereactivetowardselectrophilicreactionoccursat orthoand parapositionof -OHgroupalso-OHgroupis activatoin nature .


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