1.

ExplainHund.srule of maximum multiplicity .

Answer»

SOLUTION : Thisruledealwith thefillingof electronsintothe orbitalbelongingto thesamesubshell .
Rule :Pairingof ELECTRONIN theorbitalsnot takepalceuntileachorbitalbelongingto thatoccupied. Insubshelllfirstoneelectronarrangeand thanafter pairingwill takepalce.
Thereare THREE p fived andsevenf orbitalsthereforethe pairingof electronswill startin the p , da and f orbitalswith theentryof `4^(th), 6^(th)`and `8^(th)`electronrespectively.
Example: N (Z =7)in `1s^(2) 2s^(2)2p_(x)^(1) 2p_(x)^(1)2p_(z)^(1)`
and ` O (z = 8)` in`1s^(2)2s^(2) 2p_(x)^(2)2p_(y)^(1)2p_(z)^(1)`
typeelectronconfigurationoccurs.


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