1.

Explainthe energyof orbitaland extent ofshielding in sameshelldependson shapeoforbitals.

Answer»

Solution :Both theattractiveand repulsive interactionsdependsupon the SHELL and shapeof the orbitalin whichthe electronis present . Reasonare asfollows :
(i)s orbitalshieldsthe OUTER electronfrom the nucleusmoreeffectivelyas compared toelectronspresentin porbital
(II) Duesphericalshapeof sorbitalthe s orbitalelectronspendsmoretime closetoelectronwhichspendsmoretimein thevicinityof nucleusincomparison tod- orbitalelectron.
(iii)Effectivenucleuscharge: As the angularso s-orbitalis moretightlybond TOTHE nucleusthe p- orbitalelectrond-orbitalelectron .
Result : The ENERGYOF `s ltp ltd lt f`


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