1.

Figure shows plot of (PV)/(T) and P for 2gm of oxygen gas at two different temperatures (i) The significance of dotted line (ii) The relation between T_(1) and T_(2) (iii) The value of (PV)/(T) where the curves meet on the x-axis.

Answer»

Solution :(i) For the dotted line, `(PV)/(T)`= constant
It represents the behaviour of an ideal gas.
(II) The gas equation PV=RT is true only at high temperature in fig, curves for `T_(1)` is CLOSER to the dotted line than curve for `T_(2)`
Hence the relation between `T_(1) and T_(2)` is `T_(1) gt T_(2)`
(III) `(PV)/(T)=mu, R`. So, the value of `(PV)/(T)` where the curves meet on the Y-axis gives the value of `mu R`.
In this case `mu=(m)/M=(2)/(32)=(1)/(16)`
`(PV)/(T)=mu R=(1)/(16) XX 8.31 =0.519J//K`


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