1.

Find the `DeltapH(` initial `pH -` final `pH)` when `100 ml 0.01M HCl` is added in a solution containing `0.1m` moles of `NaHCO_(3)` solution of negligible volume `(k_(a_(1))=10^(-7),k_(a_(2))=10^(-11)` for `H_(2)CO_(3)) :`A. `6+2 log 3`B. `3-2 log 3`C. `3+2log2`D. `6-2log 3`

Answer» Correct Answer - 1
pH of `NaHCO_(3)` solution `=9`
Now `H^(+)+HCO_(3)^(-)rarr H_(2)CO_(3)`
`:.` no. of mmole of HCl remaining `=1-0.1=0.9` mmole `" ":. pH=-log(9xx10^(-3))=-2log3+3`


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