1.

Find the minimum attainable pressure of one mole of an ideal gas if during its expansion its temperature and volume are related as T=T_(0)+alphaV^(2) where T_(0)" and "alpha are positive constants.

Answer»

Solution :GIVEN that one mole of gas is used, thus from gas law, we have PV = RT or
`P=(RT)/V=R/V(T_(0)+alphaV^(2))""["as "T=T_(0)+alphaV^(2)]`
Here pressure P will be minimum when
`(dP)/(DV)=0" or "(dP)/(dV)=(RT_(0))/V^(2)+alphaR=0" or "V=sqrt(T_(0)/alpha)`
Thus pressure of gas is minimum when its volume is `V=sqrt(T_(0)/alpha)` and at this volume its temperature is given as `T=T_(0)+alphaV^(2)`
`T=T_(0)+alpha(sqrt(T_(0)/alpha))^(2)=2T_(0)`
Thus minimum value of pressue is `rArr P_(MIN)=(RT)/V=(R(2T_(0)))/sqrt(T_(0)//alpha)=2Rsqrt(T_(0)alpha)`


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