1.

Following reactions may occur at cathode during the electrolysis of aqueous CuCl2 solution using Pt electrodes:Cu2+(aq) + 2 e-  → Cu(s) :E° = +0.34 VH+(aq) + e- → 1/2H2(g) : E° = 0.00 VOn the basis of their standard electrode potential values, which reaction is feasible at cathode and why ?

Answer»

Cu2+(aq) + 2 e-  → Cu(s)

Becaus.e it has higher reduction potential.

Detailed Answer: 

As reaction with higher value of standard electrode potential occurs at cathode get reduced. So, the reaction occurring at cathode is

Cu2+(aq) + 2 e-  → Cu(s)



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