1.

Following solutions were prepared by mixing different volumes of NaOH and HCl of different concentrations: a. 60 mL `(M)/(10) HCl + 40 mL (M)/(10)` NaOH b. 55 mL `(M)/(10) HCl + 45 mL (M)/(10)` NaOH c.75 mL `(M)/(5) HCl + 25 mL (M)/(5)` NaOH d. 100 mL `(M)/(10) HCl + 100 mL (M)/(10)` NaOH pH of which one of them will be equal to 1 ?A. IVB. IC. IID. III

Answer» Correct Answer - D
`75 mL(M)/(5) HCl+25mL (M)/(5)NaOH`
Milliequivalent of HCl `=75 mL " of" (M)/(5) HCl=(1)/(5)xx75=15`
Milliequivalent of NaOH
`=25 mL " of" (M)/(5) NaOH`
`=(1)/(5)xx25=5`
`therefore` Milliequivalent of HCl left unused
=15-5=10
Volume of solution =100 mL
`therefore` Molarity of `[H^(+)]` in the resulting mixture
`=(10)/(100)=(1)/(10)`
`therefore " " pH="log" (1)/([H^(+)])`
=log (10)=1


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