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For a gaseous homogeneous reaction at equilibrium, number of moles of products are greater than the number of moles of reactants. Is KC is larger or smaller than KP? |
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Answer» For a homogeneous reaction at equilibrium, number of moles of products (np) are greater than the number of moles of reactants (nR) then ∆ng = + ve nP > nR ∆ng = + ve If ∆ng is ve, Kp value is greater than KC KP = KC . (RT)+ve KP > KC Example: PCl5 PCl3(g) + Cl2(g) 2 – 1 = 1 KP = KC (RT)1 KP > KC |
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