1.

For a gaseous homogeneous reaction at equilibrium, number of moles of products are greater than the number of moles of reactants. Is KC is larger or smaller than KP?

Answer»

For a homogeneous reaction at equilibrium, number of moles of products (np) are greater than the number of moles of reactants (nR) then ∆ng = + ve

nP > nR

∆ng = + ve 

If ∆ng is ve, Kp value is greater than KC 

KP = KC . (RT)+ve 

KP > KC 

Example: PCl5 PCl3(g) + Cl2(g) 

2 – 1 = 1 

KP = KC (RT)

KP > KC



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