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For a hypothetical reaction, the following kinetic data suggested that the overall order of this reaction is {:("[A]",[B],[C]),(mol" "dm^(-3),mol" "dm^(-3),mol" " dm^(-3) s^(-1)),(2.0,1.0,1.0),(2.0,4.0,2.0),(1.0,4.0,1.0):} |
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Answer» 3 `1=(2)^(a)(1)^(b)""…(i)` `2=(2)^(a)(1)^(b)""…(ii)` `1=(1)^(a)(4)^(b)""…(iii)` Dividing (ii) by (i) `((2)^(a)(4)^(b))/((2)^(a)(1)^(b))=(2)/(1)` `4=2 to b=1//2` Dividing (ii) by (iii) `((2)^(a)(4)^(b))/((1)^(a)(4)^(b))=(2)/(1)` `2^(a) = 2 IMPLIES a=1` `therefore` Rate law EXPRESSION is , `r=[A][B]^(1//2)` Order of reaction `=1+(1)/(2)=(3)/(2)=1.5` |
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