1.

For a particular reversible reaction at temperature T, DeltaH and DeltaS were found to be both +ve. If T_(e) is the temperature at equilibrium, the reaction would be spontaneous when

Answer»


SOLUTION :`DeltaG = DeltaH -TDELTAS`
At EQUILIBRIUM, `DeltaG =0`
` 0 = DeltaH -TDeltaS`
or `T_(e)DeltaS = DeltaH`
`T_(e) = (DeltaH)/(DeltaS)`
SINCE it is an endothermic reaction, it is favoured by high temperature so that `T gt T_(e)`.


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