1.

For an ideal gas, the work of reversible expansion under isothermal condition can be calculated by using the expression w = "-nRT" In (V_(f))/(V_(i)) A sample containing 1.0 mol of an ideal gas is expanded isothermally and reveribly to ten times of its original volume, in two separate experimentsThe expansion is carried out at 300 K and at 600 K respectively.Choose the correct option

Answer»

Work done at 600K is 20 times the work done at 300 K
Work done at 300 K is TWICE the work done at 600 K
Work done at 600 K is twice the work done at 300 K
`DeltaU = 0` in both CASES

Solution :`w = -nRT In (V_(f))/(V_(i))`.Here, N, R and In`(V_(f))/(V_(i))` are same in both the cases, therefore,
`(w_(2))/(w_(1)) = (T_(2))/(T_(1))` or `(w(600 K))/(w(300 K)) = (600 K)/(300 K) = 2`
i.e. Work done at 600 K is twice the work done at 300K.Since each case involves isothermal expansion of an ideal gas, there is no change in internal energy i.e. `DeltaU = 0`.


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