1.

For complete combustion of ethanol, `C_(2)H_(5)OH(l)+3O_(2)(g)rarr2CO_(2)(g)+3H_(2)O(l)`, the amount of heta produced as measured in bomb calorimeter, is 1364.47 kJ `mol^(-1)` at `25^(@)`. Assuming ideality the Enthalpy of combustion. `Delta_(C)H`, for the reaction will be `(R=8.314 kJ mol^(-1))`A. `-1366. 95 kJ mol^(-1)`B. `-1361.95 kJ mol^(-1)`C. `-1460.50 kJ mol^(-1)`D. `-1350.50 kJ mol^(-1)`

Answer» Correct Answer - A
`C_(2)H_(5)OH(l)+3O_(2)(g)rarr2CO_(2)(g)+3H_(2)O(l)`
`DeltaU=-1364.47 KJ//mol`
`DeltaH=DeltaU+Deltan_(g)RT`
`Deltan_(g)=-1`
`DeltaH=-1364.47+[(-1xx8.314xx298)/(1000)]`
`=-1364.47-2.4776`
`=-1366.94 KJ//mol`.


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