1.

For the cell reaction , |Cu| Cu^(2+)(aq)|Ag^(+)|Ag is E^(@) Cu^(2)|Cu=+0.34 V adb nE^(@) Ag^(+) |Ag=0.80 V and [Cu^(+2)]=0.01 and [Ag^(+)] = 1.0 "mol dm"^(-3) the emf of the cell is

Answer»

0.34 V
0.46 V
0.52 V
1.14 V

Solution :`E_("cell")=E_("cell")^(@)+(0.059)/(2)"log"([AG^(+)])/([CU^(+2)])`
`=0.80-0.34+(0.059)/(2)"log"((1.0)^(2))/(0.01)`
`=0.46 +(0.059)/(2) xx 2=0.46+0.059`
=0.52 V


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