1.

For the electrophilic substitution reaction involving nitration, which of the following sequence regarding the rate of reaction is true? (1) \( K _{ C _{6} H _{6}}> K _{ C _{6} D _{6}}> K _{ C _{6} T _{6}} \) (2) \( K _{ C _{6} H _{6}}< K _{ C _{6} D _{6}}< K _{ C _{6} T _{6}} \) (3) \( K_{ C _{6} H _{6}}= K _{ C _{6} D _{6}}= K _{ C _{6} T _{6}} \) (4) \( K _{ C _{6} H _{6}}> K _{ C _{6} D _{6}}< K _{ C _{6} T _{6}} \)

Answer»

The correct option is (3).

In nitration, rate does not depend on removal of proton as it is the fast step.



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