1.

For the equilibrium 2NOCl_((g)) hArr 2NO_((g)) + Cl_(2(g)) the value of the equilibrium constant, K_c is 3.75 xx 10^(-6) at 1069 K. Calculate the K_p for the reaction at this temperature ?

Answer»

Solution :`{:("Reaction equilibrium:", 2NOCl hArr , 2NO_((G)) + , Cl_(2(g)) ), ("Stoichiometric :", 2,2,1):}`
`therefore Deltan_((g))= sumn_("(g)product")-sumn_("(g)REACTANT")`
=(2+1)-2
=+1
At given temperature equilibrium at gas phase, the reaction between `K_p` and `K_c`.
`K_p=K_c (RT)^(Deltan)`
where , `K_c=3.75xx10^(-6), Deltan = +1 , T=1069 K`
R=0.0831 BAR L `"mol"^(-1) K^(-1)`
`therefore K_p=(3.75xx10^(-6))(1069xx0.0831)`
=`333.1 xx 10^(-6)=3.331xx10^(-4)` bar


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