1.

For the equilibrium of the reaction NH_(4) Cl(s) hArr NH_(3) (g) + HCl (g)Kp = 81 atm^(2). Total pressure at equilibrium will be x times the pressure of NH_(3). The value of x will be ........

Answer»

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Solution :
`K_(P)=PNH_(3).PHCL=P^(2)NH_(3)` (`:. PNH_(3)=PHCl`)
`PNH_(3)=sqrt(K_(P))=9` atm = PHCl
TOTAL pressure = `PHN_(3)+PHCl=18` atm
`=2 XX PNH_(3)`
`=PNH_(3)=9` atm = x
Total pressure of equilibrium
`=PNH_(3)+PHCl=9+9=18` atm
`=2 xx "partial pressure of" NH_(3)`


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