1.

For the equilibrium, PCl_(5(g))iffPCl_(3(g))+Cl_(2(g)) at 298K. K_(C)=1.8xx10^(-7) what is DeltaG^(0) for the reaction? (R=8.314JK^(-1)mol^(-1))

Answer»

Solution :`K_(P)=K_(C)(RT)^(Deltan)Deltan=n_(p)-n_(r)=2-1=1`
`T=298KR=8.314JK^(-1)mol^(-1)`
`K_(P)=(1.8xx10^(-7))(8.314xx298)=4.46xx10^(-4)`
`Delta_(r)G^(0)=-2.303RTlogK_(P)`
`=2-2.303xx8.314xx298xxlog(4.46xx10^(-4))`
`=19118.6Jmol^(-1)=19.12KJmol^(-1)`


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