1.

For the first row of transition metals the E0 value are:E0 values VCrMnFeCoNiCuM2+/M-1.18-0.91-1.18-0.44-0.28-0.25+0.34Explain the irregularity in the above values. 

Answer»

The E0 (M2+/M) values are not regular which can be explained from the irregular variation of ionization energy and sublimation energy of Mn due to half‐filled orbitals.



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