1.

For the reaction at 298 K : 2A +B to C DeltaH="400 KJ mol"^(-1) , DeltaS ="0.2 JK"^(-1) "mol"^(-1) Determine the temperature at which the reaction would be spontaneous .

Answer»

Solution :Given: T=298 K
`DeltaH=400 "J mol"^(-1) =400 "J mol"^(-1)`
`DeltaS=0.2 JK^(-1) mol^(-1)`
`DELTAG=DeltaH-TDeltaS`
If T=2000 K
`DeltaG`=400 -(0.2 x 2000) =0
if T > 2000 K
`DeltaG` will be negative
The reaction WOULD be spontaneus only BEYOND 2000 K .


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