1.

For the reaction, I^(-)+CIO_(3)^(-)+H_(2)SO_(4)rarrCI^(-)+HSO_(4)^(-)+I_(2) the correct statement (s) in the balanced equation is//are

Answer»

stoichiometric coeffiecient of `HSO_(4)^(-)` is 6
iodide is oxidised
suphur is reduced
`H_(2)O` is one of the products

Solution :The oxidation half reaction is:
`2I^(-)rarrI_(2)+2E^(-)`
The REDUCTION half rection is :
`6H^(+)+CIO_(3)^(-)+6E^(-)rarrCI^(-)+3H_(2)O`
Multiply eqn.(i) by 3 and add to eqn.(i)
`6H^(+)+CIO_(3)^(-)+6e^(-)rarrCI^(-)+3H_(2)O`
`6I^(-)rarr3I_(2)+6e^(-)`
`(6I^(-)+6H^(+)+CIO_(3)^(-)rarr3I_(2)+3H_(2)O+CI^(-))/((a) "The stoichiometry of" HSO_(4)^(-) is 6`
The `H^(+) "IONS are provided by"H_(2)SO_(4)"or"HsO_(4)^(-)` ion
(b) `I^(-)` ions are oxidisded to `I_(2)`
(d) `H_(2)O` is one of the products formed in the REDOX rection.


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