1.

For the sparingly soluble salts, an equilibrium is established between the undissolved solid unit and ions of the dissolved salt. For a solution of the salt like A_x B_y. A_x B_y =xA^(y+)+yB^(x-) K_(sp)=[A^(y+)]^x [B^(x-)]^y For precipitationto occur , the ionic product must be greater than K_(sp). What is the minimum concentration of OH^- ions required to precipitate Fe(OH)_3 from a 0.001 M solution of FeCl_3 (K_(sp) of Fe(OH)_3 =1xx10^(-36) )

Answer»

`1xx10^(-12)`
`1xx10^(-11)`
`1xx10^(-18)`
`1xx10^(-16)`

Solution :`K_(sp)=[Fe^(3+)][OH^-]^3`
`[Fe^(3+)]=[FeCl_3]`=0.001 M
`[OH^-]^3 =(1xx10^(-36))/0.001 =1xx10^(-33)`
`THEREFORE [OH^-]=1xx10^(-11)`


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