1.

For which of the following reaction is aluminium isopropoxide a specific reagent

Answer»

`R-NO_(2) rarr R-NOH`
`RCOOR rarr RCH_(2)OH`
`RCH=CHCHO rarr RCH=CH-CH_(2)OH`
`RCH=CH-CH_(2)CL rarr RCH=CHCH_(3)`

Solution :It is a SPECIFIC reagent for the reduction of carbonyl group. Thus aluminium ISOPROPOXIDE may be used for reducing aldehydes and ketones containingsome other reducible group such as a double bond or a NITRO group.
[Meerwin-Pondorf-Verley (MPV) reduction].


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