1.

Four different identical vessels at same temperature contains one mole each of C_(2)H_(6),CO_(2),Cl_(2) and H_(2)S at pressure P_(1),P_(2),P_(3) and P_(4) respectively. The value of van der Waal's constnat 'a' for C_(2)H_(6),CO_(2),Cl_(2) and H_(2)S is 5.562,3.640,6,579 and 4.490 atm L^(2) "mol"^(-2) respectively. Then:

Answer»

`P_(3)ltP_(1)ltP_(4)ltP_(2)`
`P_(1)ltP_(3)ltP_(2)lt_(4)`
`P_(2)ltP_(4)ltP_(1)ltP_(3)`
`p_(1)=p_(2)=p_(3)=p_(4)`

ANSWER :a


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