1.

Four species are listed below: (i) HCO_3^- (ii) H_3O^+ (iii)HSO_4^- (iv)HSO_3F Which one of the following is the correct sequence of their acid strength ?

Answer»

`iii LT I lt iv lt ii`
`iv lt ii lt iii lt i`
`ii lt iii lt I lt iv`
`I lt iii lt ii lt iv `

Solution :`HSO_3F` is the super acid. Its ACIDIC strength is greater than any given SPECIES. The `pK_a` value of other species are given below:
`HSO_3^(-) to` 10.25
`H_3O_(+) to` -1.74
`HSO_4^(-) to` 1.92
Lesser the `pK_a` value, higher will be its acidic strength. Hence SEQUENCE of acidic strength will be,`HSO_3F gt H_3O^(+) gt HSO_4^(-) gt HSO_3^(-)`


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