1.

From the data given below at 298 K for the reaction : CH_(4)(g) + 2O_(2)(g) rarr CO_(2)(g) + 2H_(2)O(l) Calculate the enthalpy of formation of CH_(4)(g) at 298 K. Enthalpy of reaction is = -893.5 kJ Enthalpy of formation of CO_(2)(g) = 393. kJ mol^(-1) Enthalpy of formation of H_(2)O(l) = 286.0 kJ mol^(-1).

Answer»

Solution :`Delta H = Delta H_(f)CO_(2)(g) + 2DELTA H_(f)H_(2)O(L) - Delta H_(f)CH_(4)(g) - Delta H_(f)O_(2)(g)`
`-890.5 KJ = -393.5 kJ + 2 XX -286 kJ - Delta H_(f)CH_(4)(g) - 0`
`Delta H_(f)CH_(4) = -75.0 kJ`.


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