1.

From the following sequence of reactions , [A] (C_(6)H_(12)) overset(HCl)(rarr) (B) (C_(6) H_(13)Cl)+ (C) (C_(6)H_(13)Cl) react with AgNO_(3) to give white ppt. [B]overset("Alc." KOH)(to) (D)(An isomer of A ) gives positive test with Br_(2)//C Cl_(4) [D] overset("Ozonelysis")(to)(E) gives positive iodoform test and negative Fehling's test . [A] overset("Ozonolysis")(to) (F) + (G) , both F and G give positive Tollen's test . [F] + [G] underset(Delta)overset("Conc." NaOH)(to) HCOONa + alcohol The structure A and B respectively are :

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ANSWER :A


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