1.

Generallythe firstionizationenergyincreases along aperiod.Butthere aresome exceptions. One whichis not anexception is

Answer»

N andO
NA andMg
Mg and A1
Be and B

Solution :Inspiteof highernuclearchargethe ionizationenthalpyof O islowerthan thatof Nbecause Nhas exactlyhalf- filledmorestableelectronicconfigurationbut Odoesnot. Similarlyin spiteof highernuclearcharge, ionizationenthalpyofA1 islowerthan thatof Mgbecausein case of A1a lessstronglyattracted 3p- ELECTRONIS to beremoved3s- ELECTRON is to beremoved. Likewise, in SPITE of highernuclearcharge , the ionizationenthalpyof B islower than thatof Bebecausein caseof B , alessstronglyheld 2P- electron is to beremovedwhile incase of Mga morestronglyheld2s- electron isto beremoved.
Howeverin case of Naand Mgionizationenthalpyincreasesas teh nuclearchargeincreases. Thereforeoption (b ) is correct.


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