InterviewSolution
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Give an account of the spectral series of hydrogen atom. |
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Answer» Hydrogen atom has a single electron. Its spectrum consists of series of spectral lines. Lyman series : Lyman Series consists of spectral lines corresponding to the transition of an electron from higher energy orbits n = 1 and n2 = 2,3,4… These lines belong to Ultraviolet region. Balmer series : Balmer series consists of spectral lines emitted during transitions of electrons from higher energy orbits to the second orbit. n1 = 2 and n2 = 3,4,5… .These lines lie is the visible region. Paschen series : Paschen series consists of spectral lines emitted when electron jumps higher energy orbits to the third orbit n1 = 3 and n2 = 4,5,6 … .These lines lie in the infrared region. Brackett series : Brackett series consists of spectral lines emitted during transitions of electrons from higher energy orbits to fourth orbit. n1 = 4 and n2 = 5,6,7… Pfund series : Pfund series consists spectral lines emitted during transition of electrons from higher energy orbits to the fifth orbit. . n1 = 5 and n2 = 6,7,8… . These lines lie in infrared region . The transition from (n1 + 1) to n1 corresponding to Ist member or longest wavelength of the series. The transition from (infinity) state to ‘n1’ state corresponds to the last number or series limit or shortest wavelength of the series. |
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