1.

Give one method for industrial preparation and one for laboratory preparation of CO and CO_2 each.

Answer»

Solution :Carbon monoxide (CO):
CO is commercially prepared by passing steam over hot coke. The reaction involved is as follows:
`2C_((s)) + O_2 underset"COMBUSTION"overset"Incomplete"to 2CO_((g))`
In the laboratory, CO is prepared by the dehydration of formic ACID with conc. `H_2 SO_4` at 373 K. The reaction involved is as follows:
`underset"Formic acid"(HCOOH) overset(H_2SO_4) toCO+ H_2O`
Carbon dioxide `(CO_2)`:
In the laboratory, `CO_2` can be prepared by the action of dilute hydrochloric acid on calcium carbonate. The reaction involved is as follows:
`CaCO_3 + 2HCl to CaCl_2 + CO_2 + H_2O`
`CO_2` is commercially prepared by heating limestone. The reaction involved is as follows :
`C_((s)) + O_(2(g)) underset"combustion"overset"COMPLETE"to CO_(2(g))`


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