1.

Give the mathematical expression for the equlibrium constant `(K_(c) " and " K_(p))` for the ractions `(i) H_(2)(g) + I_(2)(g) hArr2HI(g)` `(ii) N_(2)(g) +3H_(2)(g) hArr 2NH_(3)(g)` `(iii) PCl_(5)(g) hArr PCl_(3)(g)+Cl_(2)(g)`

Answer» `(i) " "K_(c) =([HI]^(2))/([H_(2)][I_(2)]) , K_(p) = K_(c)(RT)Deltang=K_(c)(RT)^(2-2)=K_(c)`
`(ii)" "K_(c)= ([NH_(3)]^(2))/([N_(2)][H_(2)]^(3)), K_(p)=K_(c)(RT)Deltang=K_(c)(RT)^(2-4) = K_(c)(RT)^(-2)`
`(iii) " "K_(c) = ([PCl_(3)][Cl_(2)])/([PCl_(5)]), K_(p)=K_(c)(RT)Deltang=K_(c)(RT)Deltang = K_(c)(RT)^(2-1)=K_(c)(RT)`


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