Give the order of the stabilities of the following : (i) (a) PhCH_2^(oplus) (b) Ph_2C overset (oplus) H ( c) Me_2Ch^(oplus) (d) Me_3C^(oplus) ( e) C_2 H_5^(oplus) (f) Ch_3^(oplus) (ii) (1) PH_3 dot C (b) Ph dot C H_2 ( c) Me_3 dot C (d) dot C_2 H_5 ( e) dot C H_3 (iii) (a) b) Ph_3C^(Ө) ( c) Me_2 CH^(Ө) (d) overset (Ө) CH_3 ( e) overset (Ө) C_2 H_5 (f) Me_3 C^(Ө).

Give the order of the stabilities of the following : (i) (a) PhCH_2^(

1.	Give the order of the stabilities of the following : (i) (a) PhCH_2^(oplus) (b) Ph_2C overset (oplus) H ( c) Me_2Ch^(oplus) (d) Me_3C^(oplus) ( e) C_2 H_5^(oplus) (f) Ch_3^(oplus) (ii) (1) PH_3 dot C (b) Ph dot C H_2 ( c) Me_3 dot C (d) dot C_2 H_5 ( e) dot C H_3 (iii) (a) b) Ph_3C^(Ө) ( c) Me_2 CH^(Ө) (d) overset (Ө) CH_3 ( e) overset (Ө) C_2 H_5 (f) Me_3 C^(Ө).
Answer» Solution :(i) `Ph_2 CH^(OPLUS) gt PhCH_2^(oplus) gt Me_3 C^(oplus) gt Me_2 CH^(oplus) C_2 H_5^(oplus) gt CH_2^(oplus) (b gt a gt d gt c gt e gt f)` (ii) `Ph_3 DOT C gt Ph dot C H_2 gt Me_3 dot C gt dot C_2 H_5 gt dot CH_3 (a gt b gt c gt d GTE )` (ii) `a gt b gt d gt e gt c gt f` (a) Aromatic (six `overline e` systems with conjugation, resonance stabilised) (b) Triphenyl methane carbanion (stabilished by resonance by three `Ph` GROUPS) (c) `overset (Ө) CH_3` (`1^@` carbanion) ( d) `overset (Ө)C_2 H_5` (ethyl carbanion) (e) `2^@` Carbanion (f) `3^@` carbanion (the stability of carbanion : `1^@ gt 2^@ gt 3^@`).