1.

Given `Delta G^(@) = -n F E_("cell")^(@)` and `DeltaG^(@) = - RT` ln K The value of n = 2 will be given by the slope of which line in the fig. A. OAB. OBC. OCD. OD

Answer» Correct Answer - B
Plot of ln K vs. `E_("cell")^(@)` will have slope = `(1)/(2) (RT)/(F)` .
`Delta G^(@) = - n FE _(cell)^(@) and Delta G^(@) = - RT ln K `
`therefore - n FE_(cell)^(@) = - RT ln K `
`therefore E_("cell")^(@) = (RT)/(nF) ln K = (RT)/(2F) ln K `
This is an equation of straight line
Slope = `(RT)/(2F) = (8.314 xx 298)/(2 xx 96500) = 0.0128`


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