1.

Given that the bond energies of H - H and CI - CI are 430 kJ"mol"^(-1) and 240 kJ"mol"^(-1) respectively and Delta_(f)H for HCI is -90 kJ"mol"^(-1), bond enthalpy of HCI is

Answer»

`254 kJ"mol"^(-1)`
`290 kJ"mol"^(-1)`
`380 kJ"mol"^(-1)`
`425 kJ"mol"^(-1)`

Solution :`1/2 H_(2) + 1/2 CI_(2) to HCI`
`DeltaH = 1/2 B.E.(H-H) + 1/2B.E(CI - CI) - B.E.(H- ci)`
`-90 = 1/2(430) + 1/2(240) - B.E (H - CI)`
`therefore B.E.(H - CI) = 215 + 120+ 90 = 425 kJ"mol"^(-1)`


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