1.

Givethe orderof energyof orbitalsinmultielectronatom

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Solution :Order of energyof orbitals: Theenergyorderof orbitals of MULTI- electronatomsin ground - stateis shown in followingdiagramin itthesubsidiaryquantum NUMBER (l ) ischangethen energyof orbitalalsochange
Thusenergyorderof orbitalsalsochange
THUS energyorderoforbitals
`1slt 2s lt 3s lt 3p lt 4slt 3d `
`lt 4plt 5s lt 4dlt 5P lt 6s lt 4f lt`
order of energy
In H 2s = 2p
in other2 s `lt`2pandenergyof 2s in H `lt `
energyof2s of other etc

factors of affectingthe energy of orbitals :
(i) Theattraction of orbitaltowardsthe nucleus(ii) Theshieldingamount of outershelltoelectronof innershellorbital(ii) the ammountof effectivenuclearchargeon outershellorbital (v ) The distanceof nucleus tooutershellis dependson thevalueof l in orbital.
Shielding : Theelectronsin inner shellbetween nucleus and outershellelectrondreceasethe effectof positivechargeof nucleuson outercompleteattraction of nucleus . thiseffect iscalledshielding .
shieldingmeansdecreasein positivechargeof nucleuson outerelectronby innershellelectron.


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