1.

Grignard addition to carbonyl compounds is specific case of nucleophillic addition reaction which leads to formation of all type of alcohols (1^(@),2^(@) & 3^(@)) .In this addition the strongly nucleophlic Grignard reagent uses its electron pair to form a bond with theC - atom ofgtC=O group, where one e^(-) pair of group ,shifts out towards oxygen . It results in the formation of an intermediate species in which alkoxide ion associated withMg^(2+) and . Now addition of an intermediate of this species to give alcohol.Here P andQare respectively :

Answer»




SOLUTION :
DIOL PROTECTS aldehyde since it is more REACTIVE.
Grignard reagent reacts with keto carbon carbon since it does not REACT with (only oneequalent is given)


Discussion

No Comment Found