1.

Group 13 of periodic table consists of boron or aluminium family. Boron being the first member, shows anomalous behaviour due to its small size and high nuclear charge/size ratiom high electrone gastivity and non availability of d-electrons. All the group 13 members forms hydrides, hydroxides, halides showing +3 covalency, however boron forms electron deficient species.Which one is not correct chemical change ?

Answer»

`H_(3)BO_(3)+3NaOH rarr Na_(2)BO_(3)+3H_(2)O`
`H_(3)BO_(3)+3ROH rarr R_(3)BO_(3)+3H_(2)O`
`4BCl_(3)+3LiAlH_(4)rarr 2B_(2)H_(6)+3AlCl_(3)+3LiCl`
`3B_(2)H_(6)+6NH_(3)OVERSET("450 K")rarr 2B_(3)N_(3)H_(6)+12H_(2)`

Solution :`H_(3)BO_(3)+NaOH rarr NAB(OH)_(4) rarr NaBO_(2)+2H_(2)O`


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