InterviewSolution
Saved Bookmarks
| 1. |
Heat of solution and heat of hydration of AgF are -20.5kJmol-1 and -930kJmol-1 respectively. Calculate lattice energy of AgF. |
|
Answer» Given : Heat of solution of AgF = ΔsolnH = -ΔH1 = -20.5 kJmol-1 Heat of hydration of AgF = ΔhydH = ΔH2 = -930 kJ mol-1 Lattice energy of AgF = ΔLH = ΔH3 = ? For heat of solution, AgF(s) + aq → AgF(aq) ΔH1 For heat of hydration, Ag+(g) + F-(g) + aq → Ag+(aq) + F-(aq)ΔH2 For Lattice energy, Ag+(g) + F-(g) → AgF(s) ΔLH = ? From above equations, ∴ ΔH3 = ΔH2 – ΔH1 = -930 – (-20.5) = -909.5 kJmol-1 ∴ Lattice energy of AgF(s) = -909.5 kJ mol-1 |
|