1.

Heats of combustion of benzene, carbon and hydrogen are - 782, -94, -68 kcal mol^(-1) respectively. Calculate heat of formation of benzene.

Answer»

Solution :`C_(6)H_((s))+O_(2)(g)to 6CO_(2)(g)+3H_(2)O_((l)),DeltaH_(1)=-782k.cal`
`C_((s))+O_(2)(g)to CO_(2)(g),DeltaH_(2)=-94Kcal`
`H_(2)(g)+1/2O_(2)(g)to H_(2)O_((l)),DELTAH=-68Kcal `
The required EQUATION is `6C_((s))+3H_(2)(g)to C_(6)H_(6)(l),DeltaH=?`
Heat of formation of benzene =`DeltaH=-DeltaH_(1)+6DeltaH_(2)+3DeltaH_(2)=+14Kcal`.


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