1.

Henry's law constant for solubility of methane In benzene is4.2xx 10^(-5) mm Hg at a particular constant temperature At this temperature calculate the solubility of methane at (i) 750 mm Hg (ii) 840 mm Hg

Answer»

Solution :`(K _(H))_("BENZENE")= 4.2 xx 10 ^(5) MM Hg,` Solubility of mehhane = ? P = 750 mm Hg. P = 840 mm Hg
According to Henry.s Law.
`P = K _(11) X _("solution")`
750 mm Hg `= 4.2 xx 10 ^(-5) mm HG . x _("solution")`
`implies x _("solution") = (750)/( 4.2 xx 10 ^(-5))` i.e., solubility `= 178.5 xx 10 ^(5)`
Similary at `P = 840 mm Hg`
Solubility `= (840)/( 4.2 xx 10 ^(-5)) = 200 xx 10 ^(-5)`


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