InterviewSolution
Saved Bookmarks
InterviewSolution
| 1. |
Houw will You distinguish PEimatr cmineSeconda& amine e testic&y amineby itEous acidCl |
|
Answer» 1) Primary amines react with nitrous acid to form alcohols and nitrogen gas. CH3NH2 +O=N–OH ----[CH3 –N=N-OH] +H20 (unstable)[CH3 –N=N-OH]-----CH3OH + N2 Aliphatic diazonium compound is unstable because of absence of resonance stabilisation. 2)Secondary amines react with nitrous acid to form N-nitroso amines which are water insoluble yellow oils. (CH3)2NH+HO–N=O---(CH3)2N – N = O+H2O 3)Tertiary amines react with nitrous acid to form trialkyl ammonium nitrite salts which are soluble in water. (CH3)3 N + HONO -----(CH3)3 NHNO2+ |
|