1.

How do atomic radii of transition elements in a given series vary with increase in atomic number? What is your observation on atomic radii of 4d and 5d series of transition elements? Discuss the phenomenon involved, if any.

Answer»

The 4d and 5d series of transition elements in each group have the same atomic radii. This is due to lanthanide contraction.

The steady decrease in the size of the atoms or ions from lanthanum to lutetium is known as lanthanide contraction.

As the atomic number increases in the lanthanide series, the new electron goes to the inner 4f orbitals. The shielding effect of a 4f electron is poor. As a result, the attraction of the outer electrons by the nucleus increases and this tends to a decrease in the size.



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