1.

How do you account for formation of ethane during chlorination of methane ?

Answer»

SOLUTION :Chlorination of methane is a free radical reaction which OCCURS by the FOLLOWING mechanism :

From the above mechanism, it is evident that during propagation step, `oversetdot(CH_3)` free radicals are produced which may undergo THREE reactions , i.e. (i)-(iii). In the chain termination step , the two `oversetdot(CH_3)` free radicals combine together to FORM ethane `(CH_3-CH_3)` molecules .


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