1.

How doatomic radiivaryin a period andin agroup ? How doyou explain thevariation ?

Answer»

SOLUTION :Withina group , the atomicradiusincreasesdown the group. Thisis because a newenergyshell (i.e., principal quantum numberincreasesby unity) is ADDED at each succeedingelementwhile thenumber OFELECTRONS in THEVALENCE shellremainsto be thesame. In otherwordsthe ELECTRONSIN thevalenceshell ofeachsucceedingelementliefartherand farther awayfrom thenucleus.As a resultthe force ofattraction of the nucleus for thevalenceelectronsdecreases andhencetheatomicsizeincreases.
In contrast the atomicsize decreasesas wemovefrom leftto rightin a period. Thisis because thatwithin a period the outherelectrons remain in the sameshell but thenuclearchargeincreasesby oneunitat eachsucceedingelement . Dueto thisincreased nuclearcharge , the attraction of the numberfor theouther electrons increases and hencethe atomicsizedecreases.


Discussion

No Comment Found