1.

How does water add on to propyne? Give the equations and explain.

Answer»

Solution :`CH_(3)-C-=CH+HOHunderset(He^(2+))overset(H_(2)SO_(4))to[CH_(3)-underset(OH)underset(|)C=CH_(2)]toC_(3)-underset(O)underset(||)C-CH_(3)`
In the first setp, water ADDS on to propyne following Markovnikov rule to form propane-2ol. Being an enol, it is unstable and UNDERGOES TAUTOMERISATION to form stable propanone.


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