1.

How is boron obtained from borax ? Give chemical equations with reaction conditions and its reaction with HCI.

Answer»

Solution :`Na_(2)B_(4)O_(7).10H_(2)O+H_(2)SO_(4) rarr Na_(2)SO_(4) rarr Na_(2)SO_(4)+ underset ("Tetraboric acid") (H_(2)B_(4)O_(7)) +10H_(2)O`
`H_(2)B_(4)O_(7)+5H_(2)Orarr underset ("Boric acid")(4H_(3)BO_(3))`
`2H_(3)BO_(3) overset ("RED HEAT")rarr underset("Boric oxide")(B_(2)O_(3))+3H_(2)O`
`B_(2)O_(3)+3Mg overset ("heat ")rarr2B+3MgO`
with dry HCI , `B_(2) H_(6)` evolves `H_(2)` gas
`B_(2) h_(6) + underset(("dry")) (HCI) rarr B_(2)H_(5)CI+H_(2)`


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