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How manay millimoles of potassium dichromate is required to oxidise 24 ml o f0.5 M Moher salt solution in acidic medium ?

Answer»


Solution :No Of millimoiles of `K_(2)Cr_(2)O_(7)` present in 24 ML Of 0.5 M solution =`24xxx0.5=12`
The balanced chemical EQAUTION for the redox reaction is
`K_(2)Cr_(2)O_(7)+6(NH_(4))SO_(4).FeSO_(4).6H_(2)O+7H_(2)SO_(4)rarrK_(2)SO_(4)+6(NH_(4))SO_(4)+3Fe_(2)(SO_(4))_(3)+Cr_(2)(SO_(4))_(3)+43H_(2)O`
From the balanced eqaution 6 moles Mohr salt are oxidised by `K_(2)Cr_(2)O_(7)` =1 MOLE
`therefore` 12 millimoles of Mohr 's salt will be oxidised by `K_(2)Cr_(2)O_(7)=(1)/(6)xx12=2` millimoles


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