1.

How many times 1 M" " CH_(3) C O O H solution should be diluted so that pH of the solution is doubled ? (K_(a) of acetic acid = 1.8 xx 10^(-5))

Answer»

20 TIMES
200 times
`5.55 XX 10^(2)` times
`5.55xx10^(4) ` times

Solution :pH of a weak ACID `=(1)/(2)[pK_(a)-log C]`
`:.x=(1)/(2) [ pK_(a)-log 1] = (1)/(2) pK_(a)`
and `2x=(1)/(2)[pK_(a)-log c]`
or `pK_(a)=(1)/(2) pK_(a)-(1)/(2)log c (.:' 2x=pK_(a)]`
or `(1)/(2) log c = - (1)/(2) pK_(a)`
or `log c = -pK_(a)=log K_(a)`
or `c=K_(a)=1.8xx10^(-5)`
`:.` Dilution`=(1)/(1.8xx10^(-5))=5.55xx10^(4)` times


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