1.

How much energy is needed to dissociate 0.05% of hydrogen gas occupying a volume of 5.6 litres under S.T.P? The binding energy of a hydrogen molecule is 4.75 eV.

Answer»

As S.T.P., 22.4 litre of hydrogen contains

6.023 x 1023 molecules

5.6 litres of hydrogen contains,

(6.023 x 1023)/(22.4) x 5.6

= 1.50575 x 1023 molecules

Number of molecules in 0.05% of hydrogen

= 1.50575 x 1023 x 0.05/100 = 7.52875 x 1019

Total energy required to dissociate the molecules

= 7.52975 x 1019 x B.E

= 7.52875 x 1019 x 4.75 eV = 3.576 x 1020 eV

= 3.576 x 1020 x 1.6 x 10-19 J = 57.22 J



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